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An interesting class of porous polymer - revisiting the structure of mesoporous α-D-Polysaccharide gels

: White, R.J.; Shuttleworth, P.S.; Budarin, V.L.; Bruyn, M. de; Fischer, A.; Clark, J.H.


ChemSusChem. Chemistry & sustainability, energy & materials 9 (2016), No.3, pp.280-288
ISSN: 1864-5631
ISSN: 1864-564X
Journal Article
Fraunhofer ISE ()
Energietechnik; Wasserstofftechnologie; thermochemischer Prozess; katalytische Materialien

The processes involved in the transformation of non-porous, native polysaccharides to their highly porous equivalents introduce significant molecular complexity and are not yet fully understood. In this paper, we propose that distinct changes in polysaccharide local short-range ordering promotes and directs the formation of meso- and micro-pores, which are investigated here using N-2 sorption, FTIR, and solid-state (CNMR)-C-13. It is found that an increase in the overall double helical amylose content, and their local association structures, are responsible for formation of the porous polysaccharide gel phase. An exciting consequence of this local ordering change is elegantly revealed using a (FNMR)-F-19 experiment, which identifies the stereochemistry-dependent diffusion of a fluorinated chiral probe molecule (1-phenyl-2,2,2-trifluoroethanol) from the meso- to the micro-pore region. This finding opens opportunities in the area of polysaccharide-based chiral stationary phases and asymmetric catalyst preparation.