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A highly porous flexible metal–organic framework with corundum topology

 
: Grünker, Ronny; Senkovska, Irena; Biedermann, Ralf; Klein, Nicole; Lohe, Martin R.; Müller, Philipp; Kaskel, Stefan

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Chemical communications 47 (2011), No.11, pp.490-492
ISSN: 0022-4936
ISSN: 0009-241X
ISSN: 1359-7345
Deutsche Forschungsgemeinschaft DFG
SPP 1362;
English
Journal Article
Fraunhofer IWS ()
metal-organic framework; MOF; oxygen; zinc; corundum; coordination polymer; hydrogen adsorption; surface-area; crystal structures; drug delivery; gas sorption; channels; methane; storage; mil-53 topology

Abstract
A flexible Metal–Organic Framework Zn4O(BenzTB)3/2 (DUT-13) was obtained by combination of a tetratopic linker and Zn4O6+ as connector. The material has a corundum topology and shows the highest pore volume among flexible MOFs.

: http://publica.fraunhofer.de/documents/N-379473.html