Hier finden Sie wissenschaftliche Publikationen aus den Fraunhofer-Instituten.

Zr(IV) and Hf(IV) based metal–organic frameworks with reo-topology

: Bon, Volodymyr; Senkovskyy, Volodymyr; Senkovska, Irena; Kaskel, Stefan


Chemical communications 48 (2012), No.67, pp.8407-8409
ISSN: 0022-4936
ISSN: 0009-241X
ISSN: 1359-7345
Deutsche Forschungsgemeinschaft DFG
SPP 1362;
Journal Article
Fraunhofer IWS ()
surface area; adsorption; metal-organic framework; MOF; zirconium; hafnium; Oberfläche; Flächeninhalt; metall-organisches Gerüst

Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.