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Zr(IV) and Hf(IV) based metal–organic frameworks with reo-topology

 
: Bon, Volodymyr; Senkovskyy, Volodymyr; Senkovska, Irena; Kaskel, Stefan

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Chemical communications 48 (2012), No.67, pp.8407-8409
ISSN: 0022-4936
ISSN: 0009-241X
ISSN: 1359-7345
Deutsche Forschungsgemeinschaft DFG
SPP 1362;
English
Journal Article
Fraunhofer IWS ()
surface area; adsorption; metal-organic framework; MOF; zirconium; hafnium; Oberfläche; Flächeninhalt; metall-organisches Gerüst

Abstract
Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.

: http://publica.fraunhofer.de/documents/N-379465.html