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Quantitative analyses of glass via laser-induced breakdown spectroscopy in argon

: Gerhard, C.; Hermann, J.; Mercadier, L.; Loewenthal, L.; Axente, E.; Luculescu, C.R.; Sarnet, T.; Sentis, M.; Viöl, W.


Spectrochimica acta. B 101 (2014), pp.32-45
ISSN: 0038-6987
ISSN: 0584-8547
Journal Article
Fraunhofer IST ()
laser-induced breakdown spectroscopy; calibration-free LIBS; local thermodynamic equilibrium; glass analysis; optical glasses

We demonstrate that elemental analysis of glass with a measurement precision of about 10% can be performed via calibration-free laser-induced breakdown spectroscopy. Therefore, plasma emission spectra recorded during ultraviolet laser ablation of different glasses are compared to the spectral radiance computed for a plasma in local thermodynamic equilibrium. Using an iterative calculation algorithm, we deduce the relative elemental fractions and the plasma properties from the best agreement between measured and computed spectra. The measurement method is validated in two ways. First, the LIBS measurements are performed on fused silica composed of more than 99.9% of SiO2. Second, the oxygen fractions measured for heavy flint and barite crown glasses are compared to the values expected from the glass composing oxides. The measured compositions are furthermore compared with those obtained by X-ray photoelectron spectroscopy and energy-dispersive X-ray spectroscopy. It is shown that accurate LIBS analyses require spectra recording with short enough delays between laser pulse and detector gate, when the electron density is larger than 1017 cm-3. The results show that laser-induced breakdown spectroscopy based on accurate plasma modeling is suitable for elemental analysis of complex materials such as glasses, with an analytical performance comparable or even better than that obtained with standard techniques.