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New phosphorus-containing quinone derivatives II: Tri- and tetraphosphorylated quinone derivatives

: Müller, P.; Fuhr, O.; Döring, M.


Heteroatom chemistry 24 (2013), No.4, pp.252-262
ISSN: 1042-7163
ISSN: 1098-1071
Journal Article
Fraunhofer LBF ()

A new synthetic approach to aromatic diols substituted with two, three, and four (similar or different) phosphorus groups via the Michael-type addition of the P-H bond containing reagents to p-benzoquinone derivatives, reoxidation, and subsequent addition of another phosphorus unit is presented. A variety of new phosphorus-containing p-hydroquinone derivatives were synthesized and fully characterized.