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High performance metal-organic-framework coatings obtained via thermal gradient synthesis

: Jeremias, F.; Henninger, S.K.; Janiak, C.


Chemical communications 48 (2012), No.78, pp.9708-9710
ISSN: 0022-4936
ISSN: 0009-241X
ISSN: 1359-7345
Journal Article
Fraunhofer ISE ()
Thermische Anlagen und Gebäudetechnik; Energieeffiziente Gebäude und Gebäudetechnik; Solarthermie; Energieeffiziente und solare Kühlung

For many possible applications of metal-organic frameworks, a coating onto a metallic support capable of both superior heat and mass transfer is required. A heated substrate in contact with a chilled solution of metal salt and linker reproducibly yields polycrystalline, highly stable, thermally conductive MOF coatings at a growth rate of 50 mu m h(-1), illustrated by the formation of Cu-3(btc)(2) as an example.