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MIL-100(Al, Fe) as water adsorbents for heat transformation purposes - A promising application

: Jeremias, F.; Khutia, A.; Henninger, S.K.; Janiak, C.


Journal of Materials Chemistry 22 (2012), No.20, pp.10148-10151
ISSN: 0959-9428
Journal Article
Fraunhofer ISE ()

The adsorption/desorption of up to 0.75 g of water vapour per g of the porous MOFs 3D-{M 3O(X)(H 2O) 2[btc] 2·nH 2O}, MIL-100 (M = Al, Fe; X = OH, F, btc = benzene-1,3,5-tricarboxylate, trimesate), occurs at small relative pressures of p/p 0 < 0.4 and a comparatively small hysteresis. Together with very good cycle stability, these properties render both MIL-100(Al and Fe) very suitable candidates for thermally driven heat pumps or adsorption chillers.