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Continuous coating of ceramic fibres by industrial-scale laser driven CVD: fibre modification and structure of interfaces


Vincenzini, P.:
Advanced structural fiber composites : Proceedings of Topical Symposium V - "Advanced Structural Fiber Composites" of the Forum on New Materials of the 9th CIMTEC - World Ceramics Congress
Faenza: Techna Srl, 1999 (Advances in science and technology 22)
ISBN: 88-86538-23-5
Topical Symposium 5 on Advanced Structural Fiber Composites <1998, Florenz>
CIMTEC, World Ceramics Congress & Forum on New Materials <1998, Florenz>
Conference Paper
Fraunhofer IWS ()
CVD; Faserbeschichtung; spektroskopische Oberflächencharakterisierung; Verbundwerkstoff

A laser induced chemical vapour deposition process (L-CVD) has been developed to treat and coat ceramic fibre bundles. This method is characterised by several advantages, among them high deposition rates and very short residence times of the fibres in the deposition chamber. Laser irradiation of SiC based fibres has been found to result in strong structural changes due to recrystallisation accompanied by evolving gaseous SiO and CO. The deposition of thin py-C layers shifts this thermal SiC fibre degradation process to significantly higher power densities, which results in coated fibres without degradation. With CH4 as precursor, layers of highly ordered pyrolytic graphite have been deposited on Nicalon fibres.